|
|
Dehydrorabelomycin + O2 <=> H+ + 3-(2-formyl-6-hydroxy-4-methylphenyl)-8-hydroxy-1,4-dioxonaphthalene-2-carboxylate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11984
|
|
|
|
8-methyltetraphene-1,5,6,11,12-pentol + O2 <=> Dehydrorabelomycin + H2O2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11983
|
|
|
|
ATP + acetyl-CoA + HCO3- <=> ADP + phosphate + malonyl-CoA + H+
|
6.4.1.2
acetyl-CoA carboxylase
6.4.1.3
propionyl-CoA carboxylase
6.4.1.4
methylcrotonoyl-CoA carboxylase
|
–
–
–
|
| |
BRENDA:
BR6444
KEGG:
R00742
MetaCyc:
ACETYL-COA-CARBOXYLTRANSFER-RXN
SABIO-RK:
542
|
|
|
|
3-(2-formyl-6-hydroxy-4-methylphenyl)-8-hydroxy-1,4-dioxonaphthalene-2-carboxylate + L-isoleucine <=> Jadomycin_A + CO2 + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11985
|
|
|
|
dTDP-beta-L-digitoxose + Jadomycin_A <=> Jadomycin_B + dTDP + H+
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-11995
|
|
|
|
UWM6 <=> 2,3-Dehydro-UWM6 + H2O
|
4.2.1
|
–
|
| |
KEGG:
R09342
MetaCyc:
RXN-11981
|
|
|
|
acetyl-CoA + malonyl-CoA + H2O + H+ <=> 3,5,7,9,11,13,15,17,19-nonaoxoicosanoate + CoA + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11975
|
|
|
|
3,5,7,9,11,13,15,17,19-nonaoxoicosanoate + H+ + NADPH + O2 <=> UWM6 + CO2 + H2O + NADP+
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-11977
|
|
|
|
2,3-Dehydro-UWM6 + O2 + NADPH + H+ <=> 8-methyltetraphene-1,5,6,11,12-pentol + H2O + NADP+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11982
|
|
